Parasite Eve - the first ever M rated game released by Square, players control NYPD office Aya Brea as she races against human extinction at the hands of the mysterious and powerful Eve. This fantastic game was a sequel to a Japanese novel of the same name, which played a big role in the surge of Japanese horror in the late 90s. Also features a stunning sound track that saw praise from industry critics and fans alike.
Uncharted: Golden Abyss - Nathan Drake lands on a portable platform in this adventure unique to Sony's Vita, making excellent use of the motion controls and touchpad.
Young Justice: Legacy - play as one of over a dozen characters from the animated series and do battle alongside Batman and other Justice League members in this action adventure romp
Castlevania Requiem: bundling two of the best entries in the series in Symphony of the Night and Rondo of Blood, get the most bang for your Dracula bucks.
F1 Career Challenge - the first Formula 1 game to feature a career mode, this game offers a surprisingly solid sim experience for a console game.
Jet Moto I remember seeing this on the demo disc when I got the original PlayStation and it was so much fun!